UAB Digital Repository of Documents 6 records found  Search took 0.02 seconds. 
1.
14 p, 2.2 MB From rational design of a new bimetallic MOF family with tunable linkers to OER catalysts / Zhang, Xuan (Katholieke Universiteit Leuven. Department of Materials Engineering) ; Luo, Jiangshui (Katholieke Universiteit Leuven. Department of Materials Engineering) ; Wan, Kai (Katholieke Universiteit Leuven. Department of Materials Engineering) ; Plessers, Dieter (Katholieke Universiteit Leuven) ; Sels, Bert (Katholieke Universiteit Leuven) ; Song, Jianxun (Zhengzhou University) ; Chen, Liugang (Zhengzhou University) ; Zhang, Ting (Institut Català de Nanociència i Nanotecnologia) ; Tang, PengYi (Institut Català de Nanociència i Nanotecnologia) ; Morante, Joan Ramon (Institut de Recerca en Energia de Catalunya) ; Arbiol i Cobos, Jordi (Institut Català de Nanociència i Nanotecnologia) ; Fransaer, Jan (Katholieke Universiteit Leuven. Department of Materials Engineering)
Innovative bimetallic MOFs offer more possibilities to further tailor the properties of MOFs, which have attracted great attention for wide applications. However, it is still a great challenge to rationally design bimetallic MOFs due to the lack of a tunable and reasonable hybrid structure architecture. [...]
2019 - 10.1039/c8ta08508k
Journal of materials chemistry A, Vol. 7, Issue 4 (January 2019) , p. 1616-1628  
2.
11 p, 1.2 MB Influence of the Amide Groups in the CO2/N2 Selectivity of a Series of Isoreticular, Interpenetrated Metal-Organic Frameworks / Safarifard, Vahid (Institut Català de Nanociència i Nanotecnologia) ; Rodríguez-Hermida, Sabina (Institut Català de Nanociència i Nanotecnologia) ; Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Bigdeli, Mina (Tarbiat Modares University. Department of Chemistry) ; Tehrani, Alireza Azhdari (Tarbiat Modares University. Department of Chemistry) ; Juanhuix, Jordi (ALBA Laboratori de Llum de Sincrotró) ; Morsali, Ali (Tarbiat Modares University. Department of Chemistry) ; Casco, Mirian E. (Universidad de Alicante. Departamento de Química Inorgánica) ; Silvestre Albero, Joaquín (Universidad de Alicante. Departamento de Química Inorgánica) ; Ramos Fernández, Enrique V. (Universidad de Alicante. Departamento de Química Inorgánica) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Here we report the use of a pillaring strategy for the design and synthesis of three novel amide-functionalized metal-organic frameworks (MOFs), TMUs-22/-23/-24, isoreticular to the recently reported imine-functionalized TMU-6 and TMU-21 MOFs. [...]
2016 - 10.1021/acs.cgd.6b01054
Crystal Growth and Design, Vol. 16, Issue 10 (October 2016) , p. 6016-6023  
3.
9 p, 962.7 KB Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yields / Garzón Tovar, Luis (Institut Català de Nanociència i Nanotecnologia) ; Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Carbonell Fernández, Carlos (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
The exceptional porosity of Metal-Organic Frameworks (MOFs) could be harnessed for countless practical applications. However, one of the challenges currently precluding the industrial exploitation of these materials is a lack of green methods for their synthesis. [...]
2015 - 10.1039/c5ta04923g
Journal of materials chemistry A, Vol. 3, Issue 41 (November 2015) , p. 20819-20826  
4.
17 p, 1.2 MB Postsynthetic Selective Ligand Cleavage by Solid-Gas Phase Ozonolysis Fuses Micropores into Mesopores in Metal-Organic Frameworks / Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ; Xu, Heng (Institut Català de Nanociència i Nanotecnologia) ; Albalad, Jorge (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein we report a novel, ozone-based method for postsynthetic generation of mesoporosity in metal-organic frameworks (MOFs). By carefully selecting mixed-ligand Zr-fcu-MOFs based on organic ligand pairs in which one ligand has ozone-cleavable olefin bonds and the other ligand is ozone-resistant, we were able to selectively break the cleavable ligand via ozonolysis to trigger fusion of micropores into mesopores within the MOF framework. [...]
2018 - 10.1021/jacs.8b09682
Journal of the American Chemical Society, Vol. 140, Issue 44 (November 2018) , p. 15022-15030  
5.
6 p, 767.9 KB Zigzag ligands for transversal design in reticular chemistry : unveiling new structural opportunities for metal-organic frameworks / Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ; Grancha, Thais (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein we describe the topological influence of zigzag ligands in the assembly of Zr(IV) metal-organic frameworks (MOFs). Through a transversal design strategy using reticular chemistry, we were able to synthesize a family of isoreticular Zr(IV)-based MOFs exhibiting the bcu - rather than the fcu - topology. [...]
2018 - 10.1021/jacs.8b07050
Journal of the American Chemical Society, Vol. 140, issue 32 (August 2018) , p. 10153-10157  
6.
23 p, 959.0 KB Spray drying for making covalent chemistry : postsynthetic modification of metal-organic frameworks / Garzón Tovar, Luis (Institut Català de Nanociència i Nanotecnologia) ; Rodríguez-Hermida, Sabina (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Covalent postsynthetic modification (PSM) of metal-organic frameworks (MOFs) has attracted much attention due to the possibility of tailoring the properties of these porous materials. Schiff-base condensation betwecn an amine and an aldehyde is one of the most common reactions in the PSM of MOFs. [...]
2017 - 10.1021/jacs.6b11240
Journal of the American Chemical Society, Vol. 139, Núm. 2 (January 2017) , p. 897-903
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