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Ruthenium Complexes with Chiral bis-Pinene Ligands : an Array of Subtle Structural Diversity
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Vaquer Malia, Lydia (Institut Català d'Investigació Química) ;
Poater, Albert (Universitat de Girona) ;
De Tovar Villanueva, Jonathan (Universitat Autònoma de Barcelona. Departament de Química) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Solà i Puig, Miquel (Universitat de Girona. Departament de Química) ;
Llobet Dalmases, Antoni (Universitat Autònoma de Barcelona. Departament de Química) ;
Sala Román, Xavier (Universitat Autònoma de Barcelona. Departament de Química)
A new chiral derivative of the N,N-bis(2-pyridylmethyl)ethylamine (bpea) ligand, Me-pinene[5,6]bpea [(−)-L1], has been prepared from a new aldehyde building block [Me-pinene-aldehyde, (−)-4] arising from the monoterpene chiral pool. [...]
2013 -  10.1021/ic302678b
Inorganic Chemistry, Vol. 52, Issue 9 (May 2013) , p. 4985-4992
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34 p, 1.2 MB |
New η3-Allylpalladium Complexes with Pyridylpyrazole Ligands : Synthesis, Characterization and Study of the Influence of N1 Substituents on the Apparent Allyl Rotation
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Montoya García, Vanessa (Universitat Autònoma de Barcelona. Departament de Química) ;
Pons Picart, Josefina (Universitat Autònoma de Barcelona. Departament de Química) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Solans Monfort, Xavier (Universitat Autònoma de Barcelona. Departament de Química) ;
Font-Bardia, Mercè (Universitat de Barcelona. Unitat de Difracció de Raig-X) ;
Ros i Badosa, Josep (Universitat Autònoma de Barcelona. Departament de Química)
The allylpalladium [Pd(η3-C3H5)(L)](BF4) (L = L1 (1), L2 (2), L3 (3), L4 (4)) complexes with pyridylpyrazole ligands 2-(5-phenyl-1H-pyrazol-3-yl)pyridine (L1), 2-(1-ethyl-5-phenyl-1H-pyrazol-3-yl)pyridine (L2), 2-(1-octyl-5-phenyl)-1H-pyrazol-3-yl)pyridine (L3), and 2-(5-phenyl-3-(pyridin-2-yl)pyrazol-1-yl)ethanol (L4) were synthesized from the appropriate pyridylpyrazole ligand and [Pd(η3-C3H5)Cl]2 in the presence of AgBF4. [...]
2007 - 10.1021/om070093u
Organometallics, Vol. 26, Issue 13 (June 2007) , p. 3183-3190
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36 p, 2.2 MB |
Design of new N,O hybrid pyrazole derived ligands and their use as stabilizers for the synthesis of Pd nanoparticles
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Guerrero, Miguel (Universitat Autònoma de Barcelona. Departament de Química) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Tristany, Mar (Université de Toulouse) ;
Pons Picart, Josefina (Universitat Autònoma de Barcelona. Departament de Química) ;
Ros i Badosa, Josep (Universitat Autònoma de Barcelona. Departament de Químicas) ;
Philippot, Karine (Université de Toulouse) ;
Lecante, Pierre (Centre d'Elaboration de Matériaux et d'Etudes Structurales) ;
Chaudret, Bruno (Laboratoire de Chimie de Coordination du CNRS)
We describe the stabilization studies of new palladium nanoparticles (Pd NPs) with a family of hybrid ligands. For this purpose, two new N,O-hybrid pyrazole derived ligands, as well as other previously reported, have been used as NP stabilizing agents following an organometallic approach. [...]
2010 - 10.1021/la1016802
Langmuir, Vol. 26, Issue 19 (October 2010) , p. 15532-15540
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37 p, 1.1 MB |
Highly Efficient Pyridylpyrazole Ligands for the Heck Reaction. A Combined Experimental and Computational Study
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Montoya García, Vanessa (Universitat Autònoma de Barcelona. Departament de Química) ;
Pons Picart, Josefina (Universitat Autònoma de Barcelona. Departament de Química) ;
Branchadell Gallo, Vicenç (Universitat Autònoma de Barcelona. Departament de Química) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Solans Monfort, Xavier (Universitat Autònoma de Barcelona. Departament de Química) ;
Font-Bardia, Mercè (Universitat de Barcelona. Unitat de Difracció de Raig-X) ;
Ros i Badosa, Josep (Universitat Autònoma de Barcelona. Departament de Química)
Several [PdCl2(L)] complexes, where L is a pyridylpyrazole ligand, have been used as precatalysts in the Heck reactions between phenyl halides and tert-butyl acrylate. The used ligands differ from each other in the substitution at N1. [...]
2008 - 10.1021/om7009182
Organometallics, Vol. 27, Issue 6 (March 2008) , p. 1084-1091
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6.
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Multi-site coordination N-phosphanylamidine ligands as stabilizers for the synthesis of ruthenium nanoparticles
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Bronger, Raymond (Université de Toulouse) ;
Dung Le, Thanh (Université de Toulouse) ;
Bastin, Stéphanie (Université de Toulouse) ;
García-Antón, Jordi (Laboratoire de Chimie de Coordination du CNRS) ;
Citadelle, Cécilia (Université de Toulouse) ;
Chaudret, Bruno (Laboratoire de Chimie de Coordination du CNRS) ;
Lecante, Pierre (Centre d'Elaboration de Matériaux et d'Etudes Structurales) ;
Igau, Alain (Université de Toulouse) ;
Philippot, Karine (Laboratoire de Chimie de Coordination du CNRS)
The stabilization of ruthenium nanoparticles is achieved by using for the first time multiple donor coordination site-type ligands, the N-phosphanylamidines Image ID:c1nj20465c-t2. gif. These ligands, in which the donor sites are directly connected to one another, lead to the formation of small ruthenium nanoparticles in the size range 1. [...]
2011 - 10.1039/c1nj20465c
New journal of chemistry, Vol. 35, Issue 11 (September 2011) , p. 2653-2660
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Influence of the self-organization of ionic liquids on the size of ruthenium nanoparticles : Effect of the temperature and stirring
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Gutel, Thibaut (Université de Lyon) ;
García-Antón, Jordi (Laboratoire de Chimie de Coordination du CNRS) ;
Pelzer, Katrin (Laboratoire de Chimie de Coordination du CNRS) ;
Philippot, Karine (Laboratoire de Chimie de Coordination du CNRS) ;
Santini, Chaterine C. (Université de Lyon) ;
Chauvin, Yves (Université de Lyon) ;
Chaudret, Bruno (Laboratoire de Chimie de Coordination du CNRS) ;
Basset, Jean-Marie (Université de Lyon)
The size of ruthenium nanoparticles is governed by the degree of self-organization of the imidazolium based ionic liquid in which they are generated from (η4-1,5-cyclooctadiene)(η6-1,3,5-cyclooctatriene)ruthenium: the more structured the ionic liquid, the smaller the size.
2007 - 10.1039/b706139k
Journal of Materials Chemistry, Vol. 17, Issue 31 (July 2007) , p. 3290-3292
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16 p, 800.3 KB |
Reactions of olefins with ruthenium hydride nanoparticles : NMR characterization, hydride titration, and room-temperature C-C bond activation
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García-Antón, Jordi (Laboratoire de Chimie de Coordination du CNRS) ;
Axet, M. Rosa (Université de Toulouse, France) ;
Jansat, Susanna (Laboratoire de Chimie de Coordination du CNRS) ;
Philippot, Karine (Laboratoire de Chimie de Coordination du CNRS) ;
Chaudret, Bruno (Laboratoire de Chimie de Coordination du CNRS) ;
Pery, Tal (Freie Universität Berlin) ;
Buntkowsky, Gerd (Institut für Physikalische Chemie) ;
Limbach, Hans-Heinrich (Freie Universität Berlin)
Surface C-C bond activation: Ruthenium nanoparticles prepared by hydrogenation of an organometallic precursor accommodate more than one hydride per surface ruthenium atom as well as various ligands, such as amines or phosphines, as shown by gas-phase, liquid, and solid-state NMR spectroscopy and titration with olefins. [...]
2008 - 10.1002/anie.200704763
Angewandte Chemie - International Edition, Vol. 47, Issue 11 (February 2008) , p. 2074-2078
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36 p, 2.1 MB |
Synthesis of new RuO2@SiO2 composite nanomaterials and their application as catalytic filters for selective gas detection
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Jansat, Susanna (Laboratoire de Chimie de Coordination du CNRS) ;
Pelzer, Katrin (Laboratoire de Chimie de Coordination du CNRS) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Raucoules, Roman (Laboratoire de Chimie de Coordination du CNRS) ;
Philippot, Karine (Laboratoire de Chimie de Coordination du CNRS) ;
Maisonnat, André (Laboratoire de Chimie de Coordination du CNRS) ;
Chaudret, Bruno (Laboratoire de Chimie de Coordination du CNRS) ;
Guari, Yannick (Université Montpellier II) ;
Mehdi, Ahmad (Université Montpellier II) ;
Reyé, Catherine (Université Montpellier II) ;
Corriu, Robert J. P. (Université Montpellier II)
RuO2@SiO2 nanomaterials are prepared using hybrid mesostructured silica (EtO)2P(O)(CH2)3SiO1. 5/x SiO2 (x = 9, 16) by anchoring the metal precursor [Ru(COD)(COT)] (COD is 1,3-cyclooctadiene, COT is 1,3,5-cyclooctatriene) inside the pores of the organized silica matrix through the phosphonate moieties. [...]
2007 - 10.1002/adfm.200700519
Advanced functional materials, Vol. 17, Issue 16 (November 2007) , p. 3339-3347
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29 p, 1008.0 KB |
Molecular water oxidation mechanisms followed by transition metals : State of the art
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Sala Román, Xavier (Universitat Autònoma de Barcelona. Departament de Química) ;
Maji, Somnath (Institut Català d'Investigació Química) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Escriche Martínez, Lluís (Universitat Autònoma de Barcelona. Departament de Química) ;
Llobet Dalmases, Antoni (Universitat Autònoma de Barcelona. Departament de Química)
One clean alternative to fossil fuels would be to split water using sunlight. However, to achieve this goal, researchers still need to fully understand and control several key chemical reactions. One of them is the catalytic oxidation of water to molecular oxygen, which also occurs at the oxygen evolving center of photosystem II in green plants and algae. [...]
2014 - 10.1021/ar400169p
Accounts of chemical research, Vol. 47, Issue 2 (February 2014) , p. 504-516
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