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26 p, 1.1 MB Polymer versus phosphine stabilized Rh nanoparticles as components of supported catalysts : implication in the hydrogenation of cyclohexene model molecule / Ibrahim, M. (Institut national polytechnique (Toulouse)) ; Garcia, M. A. S. (Universidade de São Paulo. Departamento de Química Fundamental) ; Vono, L. L. R. (Institut national polytechnique (Toulouse)) ; Guerrero Hernández, Miguel (Universitat Autònoma de Barcelona. Departament de Física) ; Lecante, P. (Centre d'Élaboration de Matériaux et d'Etudes Structurales) ; Rossi, L. M. (Universidade de São Paulo. Departamento de Química Fundamental) ; Philippot, K. (Institut national polytechnique (Toulouse))
The solution synthesis of rhodium nanoparticles (Rh NPs) was achieved from the organometallic complex [Rh(η³-C₃H₅)₃] under mild reaction conditions in the presence of a polymer (PVP), a monophosphine (PPh₃) and a diphosphine (dppb) as a stabilizer, leading to very small Rh NPs of 2. [...]
2016 - 10.1039/C6DT03104H
Dalton transactions, Vol. 45, no. 44 (Nov. 2016) , p. 17782-17791  

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