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11 p, 1.4 MB Exploiting two-dimensional morphology of molybdenum oxycarbide to enable efficient catalytic dry reforming of methane / Kurlov, Alexey (ETH Zürich. Department of Mechanical and Process Engineering) ; Deeva, Evgeniya B. (ETH Zürich. Department of Mechanical and Process Engineering) ; Abdala, Paula M. (ETH Zürich. Department of Mechanical and Process Engineering) ; Lebedev, Dmitry (ETH Zürich. Department of Chemistry and Applied Biosciences) ; Tsoukalou, Athanasia (ETH Zürich. Department of Mechanical and Process Engineering) ; Comas-Vives, Aleix (Universitat Autònoma de Barcelona. Departament de Química) ; Fedorov, Alexey (ETH Zürich. Department of Mechanical and Process Engineering) ; Müller, Christoph R. (ETH Zürich. Department of Mechanical and Process Engineering)
The two-dimensional morphology of molybdenum oxycarbide (2D-Mo2COx) nanosheets dispersed on silica is found vital for imparting high stability and catalytic activity in the dry reforming of methane. Here we report that owing to the maximized metal utilization, the specific activity of 2D-Mo2COx/SiO2 exceeds that of other Mo2C catalysts by ca. [...]
2020 - 10.1038/s41467-020-18721-0
Nature communications, Vol. 11 (October 2020) , art. 4920  

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