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5 p, 2.1 MB Light-Driven Enantioselective Organocatalytic β-Benzylation of Enals / Dell'Amico, Luca (Institut Català d'Investigació Química) ; Fernández-Alvarez, Victor M. (Institut Català d'Investigació Química) ; Maseras Cuní, Feliu (Universitat Autònoma de Barcelona. Departament de Química) ; Melchiorre, Paolo (Institució Catalana de Recerca i Estudis Avançats)
A photochemical organocatalytic strategy for the direct enantioselective β-benzylation of α,β-unsaturated aldehydes is reported. The chemistry capitalizes upon the light-triggered enolization of 2-alkyl-benzophenones to afford hydroxy- o -quinodinomethanes. [...]
2017 - 10.1002/anie.201612159
Angewandte Chemie (International ed. Internet), Vol. 56 (february 2017) , p. 3304-3308  
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