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5 p, 471.8 KB Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators / Sáez, Ruben (Universitat Autònoma de Barcelona. Departament de Química) ; McArdle, Ciaran (Henkel Ireland Operations and Research Ltd.) ; Salhi, Fouad (Henkel Corporation) ; Marquet, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ; Sebastián Pérez, Rosa Maria (Universitat Autònoma de Barcelona. Departament de Química)
A hydrogenated frustrated Lewis pair ([TMPH][HB(CF) ]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials.
2019 - 10.1039/c8sc04729d
Chemical science, Vol. 10, Issue 11 (March 2019) , p. 3295-3299  
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