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1.
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37 p, 2.3 MB |
Design of new N,O hybrid pyrazole derived ligands and their use as stabilizers for the synthesis of Pd nanoparticles
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Guerrero, Miguel (Universitat Autònoma de Barcelona. Departament de Química) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Tristany, Mar (Université de Toulouse) ;
Pons Picart, Josefina (Universitat Autònoma de Barcelona. Departament de Química) ;
Ros i Badosa, Josep (Universitat Autònoma de Barcelona. Departament de Químicas) ;
Philippot, Karine (Université de Toulouse) ;
Lecante, Pierre (Centre d'Elaboration de Matériaux et d'Etudes Structurales) ;
Chaudret, Bruno (Laboratoire de Chimie de Coordination du CNRS)
We describe the stabilization studies of new palladium nanoparticles (Pd NPs) with a family of hybrid ligands. For this purpose, two new N,O-hybrid pyrazole derived ligands, as well as other previously reported, have been used as NP stabilizing agents following an organometallic approach. [...]
2010 -  10.1021/la1016802
Langmuir, Vol. 26, Issue 19 (October 2010) , p. 15532-15540
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2.
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9 p, 1.5 MB |
Multi-site coordination N-phosphanylamidine ligands as stabilizers for the synthesis of ruthenium nanoparticles
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Bronger, Raymond (Université de Toulouse) ;
Dung Le, Thanh (Université de Toulouse) ;
Bastin, Stéphanie (Université de Toulouse) ;
García-Antón, Jordi (Laboratoire de Chimie de Coordination du CNRS) ;
Citadelle, Cécilia (Université de Toulouse) ;
Chaudret, Bruno (Laboratoire de Chimie de Coordination du CNRS) ;
Lecante, Pierre (Centre d'Elaboration de Matériaux et d'Etudes Structurales) ;
Igau, Alain (Université de Toulouse) ;
Philippot, Karine (Laboratoire de Chimie de Coordination du CNRS)
The stabilization of ruthenium nanoparticles is achieved by using for the first time multiple donor coordination site-type ligands, the N-phosphanylamidines Image ID:c1nj20465c-t2. gif. These ligands, in which the donor sites are directly connected to one another, lead to the formation of small ruthenium nanoparticles in the size range 1. [...]
2011 - 10.1039/c1nj20465c
New journal of chemistry, Vol. 35, Issue 11 (September 2011) , p. 2653-2660
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3.
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4 p, 1.2 MB |
Influence of the self-organization of ionic liquids on the size of ruthenium nanoparticles : Effect of the temperature and stirring
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Gutel, Thibaut (Université de Lyon) ;
García-Antón, Jordi (Laboratoire de Chimie de Coordination du CNRS) ;
Pelzer, Katrin (Laboratoire de Chimie de Coordination du CNRS) ;
Philippot, Karine (Laboratoire de Chimie de Coordination du CNRS) ;
Santini, Chaterine C. (Université de Lyon) ;
Chauvin, Yves (Université de Lyon) ;
Chaudret, Bruno (Laboratoire de Chimie de Coordination du CNRS) ;
Basset, Jean-Marie (Université de Lyon)
The size of ruthenium nanoparticles is governed by the degree of self-organization of the imidazolium based ionic liquid in which they are generated from (η4-1,5-cyclooctadiene)(η6-1,3,5-cyclooctatriene)ruthenium: the more structured the ionic liquid, the smaller the size.
2007 - 10.1039/b706139k
Journal of Materials Chemistry, Vol. 17, Issue 31 (July 2007) , p. 3290-3292
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4.
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16 p, 800.3 KB |
Reactions of olefins with ruthenium hydride nanoparticles : NMR characterization, hydride titration, and room-temperature C-C bond activation
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García-Antón, Jordi (Laboratoire de Chimie de Coordination du CNRS) ;
Axet, M. Rosa (Université de Toulouse, France) ;
Jansat, Susanna (Laboratoire de Chimie de Coordination du CNRS) ;
Philippot, Karine (Laboratoire de Chimie de Coordination du CNRS) ;
Chaudret, Bruno (Laboratoire de Chimie de Coordination du CNRS) ;
Pery, Tal (Freie Universität Berlin) ;
Buntkowsky, Gerd (Institut für Physikalische Chemie) ;
Limbach, Hans-Heinrich (Freie Universität Berlin)
Surface C-C bond activation: Ruthenium nanoparticles prepared by hydrogenation of an organometallic precursor accommodate more than one hydride per surface ruthenium atom as well as various ligands, such as amines or phosphines, as shown by gas-phase, liquid, and solid-state NMR spectroscopy and titration with olefins. [...]
2008 - 10.1002/anie.200704763
Angewandte Chemie - International Edition, Vol. 47, Issue 11 (February 2008) , p. 2074-2078
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5.
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36 p, 2.1 MB |
Synthesis of new RuO2@SiO2 composite nanomaterials and their application as catalytic filters for selective gas detection
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Jansat, Susanna (Laboratoire de Chimie de Coordination du CNRS) ;
Pelzer, Katrin (Laboratoire de Chimie de Coordination du CNRS) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Raucoules, Roman (Laboratoire de Chimie de Coordination du CNRS) ;
Philippot, Karine (Laboratoire de Chimie de Coordination du CNRS) ;
Maisonnat, André (Laboratoire de Chimie de Coordination du CNRS) ;
Chaudret, Bruno (Laboratoire de Chimie de Coordination du CNRS) ;
Guari, Yannick (Université Montpellier II) ;
Mehdi, Ahmad (Université Montpellier II) ;
Reyé, Catherine (Université Montpellier II) ;
Corriu, Robert J. P. (Université Montpellier II)
RuO2@SiO2 nanomaterials are prepared using hybrid mesostructured silica (EtO)2P(O)(CH2)3SiO1. 5/x SiO2 (x = 9, 16) by anchoring the metal precursor [Ru(COD)(COT)] (COD is 1,3-cyclooctadiene, COT is 1,3,5-cyclooctatriene) inside the pores of the organized silica matrix through the phosphonate moieties. [...]
2007 - 10.1002/adfm.200700519
Advanced functional materials, Vol. 17, Issue 16 (November 2007) , p. 3339-3347
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6.
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17 p, 1.2 MB |
Light-driven water oxidation using hybrid photosensitizer-decorated Co3O4 nanoparticles
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De Tovar Villanueva, Jonathan (Universitat Autònoma de Barcelona. Departament de Química) ;
Romero Fernández, Nuria (Universitat Autònoma de Barcelona. Departament de Química) ;
Denisov, Sergey A. (Université Bordeaux. Institut des Sciences Moléculaires) ;
Bofill Arasa, Roger (Universitat Autònoma de Barcelona. Departament de Química) ;
Gimbert Suriñach, Carolina (Institut Català d'Investigació Química (Tarragona, Catalunya)) ;
Ciuculescu-Pradines, Diana (Centre national de la recherche scientifique (França). Laboratoire de Chimie de Coordination) ;
Drouet, Samuel (Centre national de la recherche scientifique (França). Laboratoire de Chimie de Coordination) ;
Llobet Dalmases, Antoni (Universitat Autònoma de Barcelona. Departament de Química) ;
Lecante, Pierre (Centre national de la recherche scientifique. Centre d'Elaboration de Matériaux et d'Etudes Structurales) ;
Collière, Vincen (Centre national de la recherche scientifique (França). Laboratoire de Chimie de Coordination) ;
Freixa, Zoraida (Universidad del País Vasco. Departamento de Química Aplicada) ;
McClenaghan, Nathan (Université Bordeaux. Institut des Sciences Moléculaires) ;
Amiens, Catherine (Centre national de la recherche scientifique (França). Laboratoire de Chimie de Coordination) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Philippot, Karine (Centre national de la recherche scientifique (França). Laboratoire de Chimie de Coordination) ;
Sala Román, Xavier (Universitat Autònoma de Barcelona. Departament de Química)
Cobalt nanoparticles (NPs) have been prepared by hydrogenation of the organometallic complex [Co(η3-C8H13)(η4-C8H12)] in 1-heptanol in the absence of any other stabilizer and then transformed into Co3O4 NPs using mild oxidative reaction conditions. [...]
2018 - 10.1016/j.mtener.2018.07.008
Materials today energy, Vol. 9 (September 2018) , p. 506-515
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7.
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12 p, 1.8 MB |
Ligand-Capped Ru Nanoparticles as Efficient Electrocatalyst for the Hydrogen Evolution Reaction
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Creus, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Drouet, Samuel (Université de Toulouse) ;
Suriñach, Santiago (Suriñach Cornet) (Universitat Autònoma de Barcelona. Departament de Física) ;
Lecante, Pierre (Centre d'Elaboration de Matériaux et d'Etudes Structurales) ;
Collière, Vincent (Université de Toulouse) ;
Poteau, Romuald (Université de Toulouse) ;
Philippot, Karine (Université de Toulouse) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Sala Román, Xavier (Universitat Autònoma de Barcelona. Departament de Química)
Multielectron reductions such as the hydrogen evolution reaction (HER) play an important role in the development of nowadays energy economy. Herein, the application of the organometallic approach as synthetic method allows obtaining very small, ligand-capped but also highly active ruthenium nanoparticles (RuNPs) for the HER in both acidic and basic media. [...]
2018 - 10.1021/acscatal.8b03053
ACS Catalysis, Vol. 8, Issue 12 (December 2018) , p. 11094-11102
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8.
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10 p, 2.3 MB |
Ruthenium nanoparticles supported on carbon microfibers for hydrogen evolution electrocatalysis
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Creus, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Mallón, Laura (Universitat Autònoma de Barcelona. Departament de Química) ;
Romero Fernández, Nuria (Universitat Autònoma de Barcelona. Departament de Química) ;
Bofill Arasa, Roger (Universitat Autònoma de Barcelona. Departament de Química) ;
Moya, Alicia (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ;
Fierro, J.L.G. (Instituto de Catálisis y Petroleoquímica (Madrid)) ;
Mas Balleste, Ruben (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ;
Sala Román, Xavier (Universitat Autònoma de Barcelona. Departament de Química) ;
Philippot, Karine (Centre national de la recherche scientifique (França). Laboratoire de Chimie de Coordination) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química)
Four different cathodes for the hydrogen evolution reaction (HER) have been developed by the decoration of commercial carbon microfibers with Ru nanoparticles (Ru NPs). Two types of carbon fibers have been used: pristine, as-received, carbon fibers (pCF) and carbon fibers modified by an oxidative treatment that led to the functionalization of their surface with carboxylic groups (fCF). [...]
2019 - 10.1002/ejic.201801438
European journal of inorganic chemistry, Vol. 2019, issue 15 (April 2019) p. 2071-2077
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9.
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25 p, 1.6 MB |
Ruthenium nanoparticles for catalytic water splitting
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Creus, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
De Tovar Villanueva, Jonathan (Universitat Autònoma de Barcelona. Departament de Química) ;
Romero Fernández, Nuria (Universitat Autònoma de Barcelona. Departament de Química) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Philippot, Karine (Centre national de la recherche scientifique (França). Laboratoire de Chimie de Coordination) ;
Bofill Arasa, Roger (Universitat Autònoma de Barcelona. Departament de Química) ;
Sala Román, Xavier (Universitat Autònoma de Barcelona. Departament de Química)
Both global warming and limited fossil resources make the transition from fossil to solar fuels an urgent matter. In this regard, the splitting of water activated by sunlight is a sustainable and carbon-free new energy conversion scheme able to produce efficient technological devices. [...]
2019 - 10.1002/cssc.201900393
ChemSusChem, Vol. 12, issue 12 (June 2019) , p. 2493-2514
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10.
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9 p, 4.2 MB |
The role of catalyst-support interactions in oxygen evolution anodes based on Co(OH)2 nanoparticles and carbon microfibers
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Mallón, Laura (Universitat Autònoma de Barcelona. Departament de Química) ;
Romero Fernández, Nuria (Universitat Autònoma de Barcelona. Departament de Química) ;
Jiménez, Alicia (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ;
Martín Morales, Elena (Universitat Autònoma de Barcelona. Departament de Química) ;
Aleman Lara, Jose Julian (Universidad Autónoma de Madrid. Departamento de Química Orgánica) ;
Mas Balleste, Ruben (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ;
Bofill Arasa, Roger (Universitat Autònoma de Barcelona. Departament de Química) ;
Philippot, Karine (Université de Toulouse) ;
García-Antón, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ;
Sala Román, Xavier (Universitat Autònoma de Barcelona. Departament de Química)
The performance of OER anodes based on supported nanocatalysts is highly dependent on the interactions taking place at the interface between the nanocatalyst and the employed conductive support. Herein, the versatility offered by the organometallic approach for the synthesis of metal-based nanostructures allowed preparing electrodes of tailored nanocatalyst-support interactions. [...]
2020 - 10.1039/D0CY00193G
Catalysis science & technology, Vol. 10, issue 14 (July 2020) , p. 4513-4521
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