Proton-coupled electron transfer activation of acidic weak nucleophiles Highly fluorinated urethanes and polyurethanes from polyfluorinated alcohols - Search Results

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Proton-coupled electron transfer activation of acidic weak nucleophiles. Highly fluorinated urethanes and polyurethanes from polyfluorinated alcohols / Soto Hernández, Marc ; Sebastián Pérez, Rosa María, dir. ; Marquet, Jordi, dir. ; Universitat Autònoma de Barcelona. Departament de Química
Els materials polifluorats mostren unes propietats molt interessants com per exemple alta estabilitat tèrmica i química. Per altra banda, els poliuretans (policarbamats) són uns dels materials més versàtils i utilitzats avui en dia. [...]
This thesis is focused on the reaction of aromatic isocyanates with polyfluorinated alcohols. The main drawback for this type of reactions is the low nucleophilicity of polyfluorinated alcohols, which do not react with isocyanates in standard conditions. [...]
[Barcelona] : Universitat Autònoma de Barcelona, 2014

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