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6 p, 411.3 KB First evidence of multiple octahedral A1 sites in Na-montmorillonite by 27Al multiple quantum MAS NMR / Takahashi, Takafumi (Nippon Steel Corporation. Advanced Technology Research Laboratories) ; Kaneshashi, Koji (Nippon Steel Corporation. Advanced Technology Research Laboratories) ; Saito, Koji (Nippon Steel Corporation. Advanced Technology Research Laboratories)
The configuration of hydroxyl groups around the octahedral cations of 2:1 phyllosilicate minerals has long been an important question in clay science. In the present study, Al multiple quantum (MQ) magic angle spinning nuclear magnetic resonance (MAS NMR) was applied to the local structural analysis of octahedral Al positions in a purified Na-montmorillonite. [...]
2008 - 10.1346/CCMN.2008.0560505
Clays and Clay Minerals, Vol. 56, Núm. 5 (2008) , p. 520-525  

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