Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]
Alvarez-Larena, Angel (Universitat Autònoma de Barcelona. Departament de Geologia)
Briansó, José Luis (Universitat Autònoma de Barcelona. Departament de Geologia)
Piniella, J. Francesc (Joan Francesc) (Universitat Autònoma de Barcelona. Departament de Geologia)
Farran José, Joan (Universitat Autònoma de Barcelona. Departament de Geologia)
Manríquez, Juan M. (Centro de Investigación Minera y Metalúrgica (Xile))
Chávez, Ivonne (Universidad de Santiago de Chile. Departamento de Ciencias de los Materiales)
Oelckers, Beatriz (Universidad Católica de Valparaíso (Xile). Instituto de Química)
Molins i Grau, Elies (Institut de Ciència de Materials de Barcelona)
Miravitlles Torras, Carles (Institut de Ciència de Materials de Barcelona)

Date:	1996
Abstract:	The title compound [2(1,2,3,3a,6a-ƞ)pentalene]-[l(ƞ5)-pentamethylcyclopentadienyl]diiron, [Fe2(C8H7)-(C10H15)(C8H6)], has a metallocenic structure with the two pentalene ligands adopting an eclipsed conformation. In the central pentalene ligand, all the peripheral bonds are of similar length whereas the bridge bond is longer; there are two significantly different Fe-C distances, i. e. a mean value of 2. 121(3)A for the Fe-Cbridge distances and a mean value of 2. 028(3)A for the distances from the Fe atoms to all other Catoms. In the terminal pentalene ligand, the C-C and C-Fe distances in the ring bonded to the Fe atom are all similar.
Rights:	Tots els drets reservats.
Language:	Anglès
Document:	Article ; Versió publicada
Subject:	Cristal·lografia ; Crystallography
Published in:	Acta Crystallographica. Section C: Crystal Structure Communications, Vol. 52, Issue 11 (November 1996) , p. 2754-2757, ISSN 1600-5759

DOI: 10.1107/S0108270196008037

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