Metal-organic framework-derived single atom catalysts for electrocatalytic reduction of carbon dioxide to C1 products
Han, Xu (Institut Català de Nanociència i Nanotecnologia)
Zhang, Ting (Institut Català de Nanociència i Nanotecnologia)
Arbiol i Cobos, Jordi (Institut Català de Nanociència i Nanotecnologia)

Fecha:	2023
Resumen:	Electrochemical carbon dioxide reduction reaction (eCO RR) is an efficient strategy to relieve global environmental and energy issues by converting excess CO from the atmosphere to value-added products. Single-atom catalysts (SACs) derived from metal-organic frameworks (MOF), which feature unique active sites and adjustable structures, are emerging as extraordinary materials for eCO RR. By modulating the MOF precursors and their fabrication strategy, MOF-derived SACs with specific-site coordination configuration have been recently designed for the conversion of CO to targeted products. In the first part of this review, MOF synthesis routes to afford well-dispersed SACs along with the respective synthesis strategy have been systematically reviewed, and typical examples for each strategy have been discussed. Compared with traditional M-N active sites, SACs with regulated coordination structures have been rapidly developed for eCO RR. Secondly, the relationship between regulation of the coordination environment of the central metal atoms, including asymmetrical M-N sites, heteroatom doped M-N sites, and dual-metal active sites (M-M sites), and their respective catalytic performance has been systematically discussed. Finally, the challenges and future research directions for the application of SACs derived from MOFs for eCO RR have been proposed.
Ayudas:	Agencia Estatal de Investigación PID2020-116093RB-C43 Agència de Gestió d'Ajuts Universitaris i de Recerca 2017/SGR-327 Ministerio de Ciencia e Innovación CEX2021-001214-S
Derechos:	Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original.
Lengua:	Anglès
Documento:	Article ; recerca ; Versió publicada
Publicado en:	Energy Advances, Vol. 2, Issue 2 (February 2023) , p. 252-267, ISSN 2753-1457

DOI: 10.1039/d2ya00284a

16 p, 2.7 MB

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Documentos de investigación > Documentos de los grupos de investigación de la UAB > Centros y grupos de investigación (producción científica) > Ciencias > Institut Català de Nanociència i Nanotecnologia (ICN2)
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