Per citar aquest document: http://ddd.uab.cat/record/98241
Electrochemically promoted carbon-halide bond cleavage in 4-nitrobenzyl halides
Cabán Huertas, Zahilia
Gallardo Garcia, Iluminada (Universitat Autònoma de Barcelona. Departament de Química)
Universitat Autònoma de Barcelona. Departament de Química

Data: 2011
Descripció: 35 p.
Resum: This manuscript reports the study of the carbon-halide bond cleavage in 4-nitrobenzyl halides, taking special attention to the iodide and fluoride derivatives. The electrochemical reduction mechanism has been disclosed for both compounds by terms of cyclic voltammetry and controlled potential electrolysis. In the case of 4-nitrobenzyl iodide, a first one electron irreversible wave leads to the corresponding 4-nitrobenzyl radical and iodide. However, in the case of 4-nitrobenzyl fluoride, a first one-electron reversible wave appears at –1. 02 vs. SCE followed by one electron irreversible wave. In this second electron transfer process, the cleavage of the C-F bond is taking place, so the bond cleavage reaction occurs at the dianion level. To disclose and understand the electrochemical reduction mechanisms that allows to obtain important thermodynamic and kinetic data that would help in the understanding of C-X bond cleavage. This type of bond dissociation reactions are involved in the metabolism pathways of the human body.
Drets: L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: Creative Commons
Llengua: Anglès.
Document: masterThesis
Matèria: Voltametria ; Nitrobenzè ; Reaccions químiques

Adreça alternativa: http://hdl.handle.net/2072/200351


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