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Crown ether-modified electrodes for the simultaneous stripping voltammetric determination of Cd(II), Pb(II) and Cu(II)
Serrano i Plana, Núria (Universitat de Barcelona. Departament de Química Analítica)
González-Calabuig, Andreu (Universitat Autònoma de Barcelona. Grup de Sensors i Biosensors)
Valle Zafra, Manuel del (Universitat Autònoma de Barcelona. Departament de Química)

Fecha: 2015
Resumen: This work describes the immobilization of 4-carboxybenzo-18-crown-6 (CB-18-crown-6) and 4-carboxybenzo-15-crown-5 (CB-15-crown-5) assisted by lysine on aryl diazonium salt monolayers anchored to the surface of graphite-epoxy composite electrodes (GEC), and their use for the simultaneous determination of Cd(II), Pb(II) and Cu(II) by differential pulse anodic stripping voltammetry (DPASV). These modified electrodes display a good repeatability and reproducibility with detection and quantification limits at levels of µg L−1 (ppb), confirming their suitability for the determination of Cd(II), Pb(II) and Cu(II) ions in environmental samples. The overlapped nature of the multimetal stripping measurements was resolved by employing the two-sensor array CB-15-crown-5-GEC and CB-18-crown-6-GEC, since the metal complex selectivity exhibited by the considered ligands could add some discrimination power. For the processing of the voltammograms, Discrete Wavelet Transform and Causal Index were selected as preprocessing tools for data compression coupled with an artificial neural network for the modeling of the obtained responses, allowing the resolution of mixtures of these metals with good prediction of their concentrations (correlation with expected values for an external test subset better than 0. 942).
Nota: Número d'acord de subvenció MINECO/CTQ2013-41577-P
Nota: Número d'acord de subvenció MINECO/CTQ2012-32863
Derechos: Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial i la comunicació pública de l'obra, sempre que no sigui amb finalitats comercials, i sempre que es reconegui l'autoria de l'obra original. No es permet la creació d'obres derivades. Creative Commons
Lengua: Anglès.
Documento: article ; recerca ; acceptedVersion
Materia: Crown ether-modified sensors ; Electrochemical grafting ; Metal determination ; Stripping voltammetry ; Artificial neural network
Publicado en: Talanta, Vol. 138 (June 2015) , p. 130-137, ISSN 0039-9140

DOI: 10.1016/j.talanta.2015.01.044

28 p, 536.3 KB

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