Web of Science: 10 citations, Scopus: 11 citations, Google Scholar: citations,
Design and Synthesis of a Noninnocent Multitopic Catechol and Pyridine Mixed Ligand : Nanoscale Polymers and Valence Tautomerism
Guardingo Melián, Mireia (Institut Català de Nanociència i Nanotecnologia)
Busqué Sánchez, Félix (Universitat Autònoma de Barcelona. Departament de Química)
Novio Vázquez, Fernando (Institut Català de Nanociència i Nanotecnologia)
Ruiz Molina, Daniel (Institut Català de Nanociència i Nanotecnologia)

Date: 2015
Abstract: The design and synthesis of a new redox-active ligand combining catechol and pyridine units have allowed the achievement of cobalt-based nanoscale coordination polymer particles in a single-step exhibiting a switchable valence tautomeric behavior and thermal hysteresis. The combination of polymerizing capabilities with redox-active responses in a unique ligand leads to the formation of nanoparticles exhibiting a gradual valence tautomeric interconversion in the 35-370 K temperature range. Using one single ligand to obtain these nanoparticles facilitates possible nanostructure formation methodologies. (Chemical Equation Presented).
Note: Número d'acord de subvenció MINECO/SEV-2013-0295
Note: Número d'acord de subvenció MICINN/MAT2012-38318-C03-02
Note: Número d'acord de subvenció MICINN/MAT2012-38319-C02-01
Note: Número d'acord de subvenció MICINN/CTQ2013-41161-R
Note: Número d'acord de subvenció MICINN/CTQ2010-15380
Rights: Tots els drets reservats.
Language: Anglès
Document: article ; recerca ; acceptedVersion
Published in: Inorganic Chemistry, Vol. 54, Issue 14 (July 2015) , p. 6776-6781, ISSN 1520-510X

DOI: 10.1021/acs.inorgchem.5b00598


Postprint
8 p, 562.7 KB

The record appears in these collections:
Research literature > UAB research groups literature > Research Centres and Groups (scientific output) > Experimental sciences > Catalan Institute of Nanoscience and Nanotechnology (ICN2)
Articles > Research articles
Articles > Published articles

 Record created 2019-09-23, last modified 2020-08-02



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