Web of Science: 14 citas, Scopus: 14 citas, Google Scholar: citas,
Film Quality and Electronic Properties of a Surface-Anchored Metal-Organic Framework Revealed by using a Multi-technique Approach
Liu, Jianxi (Karlsruhe Institute of Technology)
Paradinas Aranjuelo, Marcos (Institut Català de Nanociència i Nanotecnologia)
Heinke, Lars (Karlsruhe Institute of Technology)
Buck, Manfred (University of St Andrews)
Ocal García, Carmen (Institut de Ciència de Materials de Barcelona)
Mugnaini, Veronica (International Iberian Nanotechnology Laboratory)
Wöll, Christof (Karlsruhe Institute of Technology)

Fecha: 2016
Resumen: The virtually unlimited versatility and unparalleled level of control in the design of metal-organic frameworks (MOFs) has recently been shown to also entail a potential for applications based on the electrical and electronic properties of this rich class of materials. At present, methods to provide reliable and reproducible contacts to MOF materials are scarce; therefore, we have carried out a detailed, multi-technique investigation of an empty and loaded prototype MOF, HKUST-1. Epitaxial thin films of this material grown on a substrate by using liquid-phase epitaxy have been studied by cyclic voltammetry, atomic force microscopy, and quartz crystal microbalance and their quality assessed. By using an ionic liquid as the electrolyte, it is shown that redox-active molecules like ferrocene can be embedded in the pores, enabling a change in the overall conductivity of the framework and the study of the redox chemistry of guest molecules inside the MOF.
Nota: Número d'acord de subvenció EC/FP7/301110
Nota: Número d'acord de subvenció MINECO/MAT2013-47869‐C4-1‐P
Nota: Número d'acord de subvenció MINECO/SEV‐2015-0496
Nota: Número d'acord de subvenció AGAUR/2014/SGR-501
Derechos: Tots els drets reservats.
Lengua: Anglès.
Documento: article ; recerca ; acceptedVersion
Materia: Cyclic voltammetry ; Defect-free film ; Ferrocene ; Ionic liquids ; Metal-organic frameworks
Publicado en: ChemElectroChem, Vol. 3, Issue 5 (May 2016) , p. 713-718, ISSN 2196-0216

DOI: 10.1002/celc.201500486

8 p, 505.9 KB

El registro aparece en las colecciones:
Documentos de investigación > Documentos de los grupos de investigación de la UAB > Centros y grupos de investigación (producción científica) > Ciencias > Institut Català de Nanociència i Nanotecnologia (ICN2)
Artículos > Artículos de investigación
Artículos > Artículos publicados

 Registro creado el 2019-09-23, última modificación el 2020-02-08

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