Home > Articles > Published articles > Tailoring Copper Foam with Silver Dendrite Catalysts for Highly Selective Carbon Dioxide Conversion into Carbon Monoxide |
Date: | 2018 |
Abstract: | The present study outlines the important steps to bring electrochemical conversion of carbon dioxide (CO ) closer to commercial viability by using a large-scale metallic foam electrode as a highly conductive catalyst scaffold. Because of its versatility, it was possible to specifically tailor three-dimensional copper foam through coating with silver dendrite catalysts by electrodeposition. The requirements of high-yield CO conversion to carbon monoxide (CO) were met by tuning the deposition parameters toward a homogeneous coverage of the copper foam with nanosized dendrites, which additionally featured crystallographic surface orientations favoring CO production. The presented results evidence that Ag dendrites, owing a high density of planes with stepped (220) surface sites, paired with the superior active surface area of the copper foam can significantly foster the CO productivity. In a continuous flow-cell reactor setup, CO Faradaic efficiencies reaching from 85 to 96% for a wide range of low applied cathode potentials (<1. 0 V ) along with high CO current densities up to 27 mA/cm were achieved, far outperforming other tested scaffold materials. Overall, this research provides new strategic guidelines for the fabrication of efficient and versatile cathodes for CO conversion compatible with large-scale integrated prototype devices. |
Grants: | Agència de Gestió d'Ajuts Universitaris i de Recerca 2017/SGR-1246 Agència de Gestió d'Ajuts Universitaris i de Recerca 2017/SGR-327 Ministerio de Economía y Competitividad FJCI-2016-29147 Ministerio de Economía y Competitividad ENE2017-85087 Ministerio de Economía y Competitividad MAT2014-59961 Ministerio de Economía y Competitividad ENE2016-80788-C5-5-R Ministerio de Economía y Competitividad SEV-2013-0295 |
Rights: | Tots els drets reservats. |
Language: | Anglès |
Document: | Article ; recerca ; Versió acceptada per publicar |
Subject: | Electrodes ; Catalysts ; Deposition ; Foams ; Dendrons |
Published in: | ACS applied materials & interfaces, Vol. 10, Issue 50 (December 2018) , p. 43650-43660, ISSN 1944-8252 |
Postprint 27 p, 1.7 MB |