Conductive properties of triphenylene MOFs and COFs
Contreras Pereda, Noemí (Institut Català de Nanociència i Nanotecnologia)
Pané i Vidal, Salvador (ETH Zurich. Institute of Robotics and Intelligent Systems. Multi-Scale Robotics Lab)
Puigmartí-Luis, Josep (Institut de Química Teòrica i Computacional. Departament de Ciència dels Materials i Química Física)
Ruiz-Molina, Daniel (Institut Català de Nanociència i Nanotecnologia)

Date:	2022
Abstract:	Triphenylene (TP) based materials have experienced a great expansion in the latest years. TP molecules have interesting optoelectronic properties, arising from the aromatic core, which have been exploited in functional two-dimensional (2D) Metal-Organic Frameworks (MOFs) and Covalent Organic Frameworks (COFs) aside other organic polymers. In this review we summarize synthetic approaches of TP-based 2D MOFs and COFs emphasizing on the resulting morphology, crystalline domains and orientation, proven to have great impact on the properties and performance of these materials in functional devices. Specifically, we report a detailed description on the different TP-based 2D structures detailing the influence of the chemical and crystalline structure on the electronic properties, specially the in-plane and out-of-plane contribution to the electrical conductivity. Finally, we give also attention and present several examples of functional devices made out with these electronic materials with great impact in the literature as well as in future technological applications.
Grants:	Agencia Estatal de Investigación PID2020-116612RB-C33 Agencia Estatal de Investigación RTI2018-098027-B-C21 Agencia Estatal de Investigación SEV-2017-0706 European Commission 677020
Note:	Altres ajuts: the ICN2 is funded by the CERCA programme / Generalitat de Catalunya.
Rights:	Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, i la comunicació pública de l'obra, sempre que no sigui amb finalitats comercials, i sempre que es reconegui l'autoria de l'obra original. No es permet la creació d'obres derivades.
Language:	Anglès
Document:	Article ; recerca ; Versió publicada
Subject:	Triphenylene ; MOF ; COF ; Two-dimensional ; Electronic ; Functional device
Published in:	Coordination chemistry reviews, Vol. 460 (June 2022) , art. 214459, ISSN 0010-8545

DOI: 10.1016/j.ccr.2022.214459

30 p, 7.5 MB

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Research literature > UAB research groups literature > Research Centres and Groups (research output) > Experimental sciences > Catalan Institute of Nanoscience and Nanotechnology (ICN2)
Articles > Research articles
Articles > Published articles