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Aqua(glycinato)(3,4,7,8-tetramethyl-1,10-phenanthroline)copper(II) Nitrate
Alvarez Larena, Ángel (Universitat Autònoma de Barcelona. Unitat de Cristal·lografia)
Briansó, José Luis (Universitat Autònoma de Barcelona. Unitat de Cristal·lografia)
Piniella, J. Francesc (Joan Francesc) (Universitat Autònoma de Barcelona. Unitat de Cristal·lografia)
Moreno Esparza, Rafael (Universidad Nacional Autónoma de México. Departamento de Química Inorgánica)
Ruiz-Ramírez, Lena (Universidad Nacional Autónoma de México. Departamento de Química Inorgánica)
Ferrer-Sueta, Gerardo (Universidad Nacional Autónoma de México. Departamento de Química Inorgánica)

Date: 1995
Abstract: In the title compound, [Cu(C2H4NO2)(C16H16N2)-(H2O)]NO3, CuII displays distorted square-pyramidal coordination where the water molecule is in the apical position and the base is defined by the N and one of the O atoms from the glycinate ligand, and both phenanthroline N atoms. The phenanthroline chelate-ring plane (N1, C12, C11, N2, Cu) is slightly distorted from planarity, whereas the five-membered ring formed by the glycinate ligand (defined by atoms N3, C18, C17, O1 and Cu), presents a distorted half-chair conformation.
Rights: Tots els drets reservats.
Language: Anglès.
Document: article ; publishedVersion
Subject: Cristal·lografia ; Crystallography
Published in: Acta Crystallographica. Section C: Crystal Structure Communications, Vol. 51, Issue 5 (May 1995) , p. 852-854, ISSN 1600-5759

DOI: 10.1107/S0108270194013041


3 p, 324.3 KB

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 Record created 2008-07-29, last modified 2019-02-10



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