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34 p, 4.7 MB Conducting chiral nickel(ii) bis(dithiolene) complexes : Structural and electron transport modulation with the charge and the number of stereogenic centres / Abhervé, Alexandre (Université d'Angers) ; Mroweh, Nabil (Université d'Angers) ; Cauchy, Thomas (Université d'Angers) ; Pop, Flavia (Université d'Angers) ; Cui, HengBo (Condensed Molecular Materials Laboratory. RIKEN) ; Kato, Reizo (Condensed Molecular Materials Laboratory. RIKEN) ; Vanthuyne, Nicolas (Aix-Marseille Université) ; Alemany, Pere (Universitat de Barcelona. Departament de Ciència de Materials i Química Física) ; Canadell Casanova, Enric 1950- (Institut de Ciència de Materials de Barcelona) ; Avarvari, Narcis (Université d'Angers)
Nickel(ii) bis(dithiolene) complexes can provide crystalline conducting materials either in their monoanionic or neutral forms. Here we show that the use of chiral dithiolene ligands with one or two stereogenic centres, together with variation of the counter-ion in the anionic complexes, represents a powerful strategy to modulate the conducting properties of such molecular materials. [...]
2021 - 10.1039/d1tc00439e
Journal of Materials Chemistry C, Vol. 9, Issue 12 (March 2021) , p. 4119-4140  
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