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11 p, 1.1 MB An electron paramagnetic resonance spectroscopy investigation of the retention mechanisms of Mn and Cu in the nanopore channels of three zeolite minerals / Ferreira, Daniel R. (Southern Polytechnic State University. Department of Biology and Chemistry) ; Schulthess, Cristian P. (University of Connecticut. Department of Plant Science and Landscape Architecture) ; Amonette, James E. (Pacific Northwest National Laboratory) ; Walter, Eric D. (Pacific Northwest National Laboratory)
The adsorption mechanisms of divalent cations in zeolite nanopore channels can vary as a function of their pore dimensions. The nanopore inner-sphere enhancement (NISE) theory predicts that ions may dehydrate inside small nanopore channels in order to adsorb more closely to the mineral surface if the nanopore channel is sufficiently small. [...]
2012 - 10.1346/CCMN.2012.0600604
Clays and Clay Minerals, Vol. 60, Núm. 6 (2012) , p. 588-598  
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