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Synthesis of nanoscale coordination polymers in femtoliter reactors on surfaces / Guardingo Melián, Mireia (Institut Català de Nanociència i Nanotecnologia) ; Gonzalez Monje, Pablo (Institut Català de Nanociència i Nanotecnologia) ; Novio Vázquez, Fernando (Institut Català de Nanociència i Nanotecnologia) ; Bellido Vera, Elena (Institut Català de Nanociència i Nanotecnologia) ; Busqué Sánchez, Félix (Universitat Autònoma de Barcelona. Departament de Química) ; Molnar, Gábor (Centre national de la recherche scientifique (França). Laboratoire de Chimie de Coordination) ; Bousseksou, Azzedine (Centre national de la recherche scientifique (França). Laboratoire de Chimie de Coordination) ; Ruiz-Molina, Daniel (Institut Català de Nanociència i Nanotecnologia)
In the present work, AFM-assisted lithography was used to perform the synthesis of a coordination polymer inside femtoliter droplets deposited on surfaces. For this, solutions of the metal salt and the organic ligand were independently transferred to adjacent tips of the same AFM probe array and were sequentially delivered on the same position of the surface, creating femtoliter-sized reaction vessels where the coordination reaction and particle growth occurred. [...]
2016 - DOI (Digital Object Identifier)

10.1021/acsnano.5b05071
ACS nano, Vol. 10, issue 3 (March 2016) , p. 3206-3213

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