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Continuous one-step synthesis of porous M-XF6-based metal-organic and hydrogen-bonded frameworks / Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ; Garzon-Tovar, Luis (Institut Català de Nanociència i Nanotecnologia) ; Yazdi, Amirali (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Metal-organic frameworks (MOFs) built up from connecting M-XF₆ pillars through N-donor ligands are among the most attractive adsorbents and separating agents for CO₂ and hydrocarbons today. The continuous, one-step spray-drying synthesis of several members of this isoreticular MOF family varying the anionic pillar (XF₆=[SiF₆]²⁻ and [TiF₆]²⁻), the N-donor organic ligand (pyrazine and 4,4'-bipyridine) and the metal ion (M=Co, Cu and Zn) is demonstrated here. [...]
2017 - DOI (Digital Object Identifier)

10.1002/chem.201605507
Chemistry, Vol. 23, Issue 28 (May 2017) , p. 6829-6835

2 documents

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