Resultats globals: 3 registres trobats en 0.03 segons.
Articles, 3 registres trobats
Articles 3 registres trobats  
1.
8 p, 1.6 MB Self-assembly of metal-organic polyhedra into supramolecular polymers with intrinsic microporosity / Carné-Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Craig, Gavin A. (Kyoto University. Institute for Integrated Cell-Material Sciences) ; Larpent, Patrick (Kyoto University. Institute for Integrated Cell-Material Sciences) ; Hirose, Takashi (Kyoto University. Department of Synthetic Chemistry and Biological Chemistry) ; Higuchi, Masakazu (Kyoto University. Institute for Integrated Cell-Material Sciences) ; Kitagawa, Susumu (Kyoto University. Institute for Integrated Cell-Material Sciences) ; Matsuda, Kenji (Kyoto University. Department of Synthetic Chemistry and Biological Chemistry) ; Urayama, Kenji (Kyoto Institute of Technology. Department of Macromolecular Science and Engineering) ; Furukawa, Shuhei (Kyoto University. Department of Synthetic Chemistry and Biological Chemistry)
Designed porosity in coordination materials often relies on highly ordered crystalline networks, which provide stability upon solvent removal. However, the requirement for crystallinity often impedes control of higher degrees of morphological versatility, or materials processing. [...]
2018 - 10.1038/s41467-018-04834-0
Nature communications, Vol. 9 (July 2018) , art. 2506  
2.
4 p, 1.8 MB A Coordinative Solubilizer Method to Fabricate Soft Porous Materials from Insoluble Metal-Organic Polyhedra / Carné-Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Craig, Gavin A. (Kyoto University. Institute for Integrated Cell-Material Science) ; Larpent, Patrick (Kyoto University. Institute for Integrated Cell-Material Science) ; Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ; Urayama, Kenji (Kyoto Institute of Technology) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia) ; Furukawa, Shuhei (Kyoto University. Department of Synthetic Chemistry and Biological Chemistry)
Porous molecular cages have a characteristic processability arising from their solubility, which allows their incorporation into porous materials. Attaining solubility often requires covalently bound functional groups that are unnecessary for porosity and which ultimately occupy free volume in the materials, decreasing their surface areas. [...]
2019 - 10.1002/anie.201901668
Angewandte Chemie (International ed. Internet), Vol. 58, Issue 19 (May 2019) , p. 6347-6350  
3.
12 p, 1.5 MB Postsynthetic covalent and coordination functionalization of rhodium(II)-based metal-organic polyhedra / Carné-Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Albalad, Jorge (Institut Català de Nanociència i Nanotecnologia) ; Grancha, Thais (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ; Larpent, Patrick (Kyoto University. Institute for Integrated Cell-Material Science) ; Furukawa, Shuhei (Kyoto University. Department of Synthetic Chemistry and Biological Chemistry) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Metal-organic polyhedra (MOP) are ultrasmall (typically 1-4 nm) porous coordination cages made from the self-assembly of metal ions and organic linkers and are amenable to the chemical functionalization of its periphery; however, it has been challenging to implement postsynthetic functionalization due to their chemical instability. [...]
2019 - 10.1021/jacs.8b13593
Journal of the American Chemical Society, Vol. 141, issue 9 (March 2019) , p. 4094-4102  

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