Ionic liquids-Kaolinite nanostructured materials. Intercalation of pyrrolidinium salts
Letaief, Sadok (University of Ottawa. Centre for Catalysis Research and Innovation)
Detelleir, Christian (University of Ottawa. Department of Chemistry)

Data:	2008
Resum:	Ionic liquids intercalated in kaolinite constitute a novel class of nanostructured material. Kaolinite-pyrrolidinium halide intercalates have been prepared successfully by reacting the pyrrolidinium salts with kaolinite which was preintercalated with dimetyl sulfoxide (DMSO) using the melt condition under N. X-ray diffraction, C magic angle spinning nuclear magnetic resonance, differential thermal analysis (DTA)-thermal gravimetric analysis, and Fourier transform infrared spectroscopy confirm the displacement of DMSO during the intercalation process. Based on results from the various characterization techniques, a structural model is proposed in which one mole of the pyrrolidinium salt covers two or three structural units of kaolinite, depending on the structure and size of the salt. The thermal stability was improved remarkably after intercalation of the pyrrolidinium salts, compared to the pre-intercalate. The DTA-TGA data show that the largest number of organic units released and decomposed, occurs under N flow, at temperatures ranging from 260 to 340°C, depending on the nature of the intercalated organic salts.
Drets:	Tots els drets reservats.
Llengua:	Anglès
Document:	Article ; recerca ; Versió publicada
Matèria:	CP/MAS NMR ; FTIR ; Intercalation ; Ionic Liquids ; Kaolinite ; Nanohybrid Materials ; Nanostructured Materials ; Pyrrolidinium ; TGA ; XRD
Publicat a:	Clays and Clay Minerals, Vol. 56, Núm. 1 (2008) , p. 82-89, ISSN 1552-8367

DOI: 10.1346/CCMN.2008.0560107

8 p, 255.9 KB  Accés restringit a la UAB

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