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14 p, 11.0 MB Dynamics and Site Isolation : Keys to High Propane Dehydrogenation Performance of Silica-Supported PtGa Nanoparticles / Payard, P.-A. (ETH Zürich. Department of Chemistry and Applied Biosciences) ; Rochlitz, L. (ETH Zürich. Department of Chemistry and Applied Biosciences) ; Searles, K. (ETH Zürich. Department of Chemistry and Applied Biosciences) ; Foppa, Lucas (ETH Zürich. Department of Chemistry and Applied Biosciences) ; Leuthold, B. (ETH Zürich. Department of Chemistry and Applied Biosciences) ; Safonova, O. V. (Paul Scherrer Institut (Suïssa)) ; Comas-Vives, Aleix (Universitat Autònoma de Barcelona. Departament de Química) ; Copéret, Christophe (ETH Zürich. Department of Chemistry and Applied Biosciences)
Nonoxidative dehydrogenation of light alkanes has seen a renewed interest in recent years. While PtGa systems appear among the most efficient catalyst for this reaction and are now implemented in production plants, the origin of the high catalytic performance in terms of activity, selectivity, and stability in PtGa-based catalysts is largely unknown. [...]
2021 - 10.1021/jacsau.1c00212
JACS Au, Vol. 1, Issue 9 (September 2021) , p. 1445-1458  

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