Carborane bis-pyridylalcohols as linkers for coordination polymers : synthesis, crystal structures and guest-framework dependent mechanical properties
Ying Tsang, Min. (Institut de Ciència de Materials de Barcelona)
Rodríguez-Hermida, Sabina (Institut Català de Nanociència i Nanotecnologia)
Stylianou, Kyriakos C. (Institut Català de Nanociència i Nanotecnologia)
Tan, Fangchang (Institut de Ciència de Materials de Barcelona)
Divya, Negi (Institut de Ciència de Materials de Barcelona)
Teixidor, Francesc (Institut de Ciència de Materials de Barcelona)
Viñas, Clara (Institut de Ciència de Materials de Barcelona)
Choquesillo-Lazarte, Duane (Instituto Andaluz de Ciencias de la Tierra)
Verdugo-Escamilla, Cristóbal (Instituto Andaluz de Ciencias de la Tierra)
Guerrero, Miguel (Universitat Autònoma de Barcelona. Departament de Física)
Sort Viñas, Jordi (Universitat Autònoma de Barcelona. Departament de Física)
Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró)
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Giner Planas, José (Institut de Ciència de Materials de Barcelona)
Date: |
2017 |
Abstract: |
We report the synthesis and characterization of six novel coordination polymers (CPs) based on M(II) (M: Zn and Co), di-, tri-, and tetracarboxylate linkers and two novel bis-pyridylalcohol 1,7-bis{(pyridin-n'-yl)methanol}-1,7-dicarba-closo-dodecaboranes (n' = 3, L1; n' = 4, L2) ligands. The polycarboxylates are terephthalic acid (H₂BDC), 1,3,5-benzenetricarboxylic acid (H₃BTB), and 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H₄TCPB). Structural description of CPs reveals the flexibility of the carborane ligands and their ability to construct extended structures. The CP containing Co(II), BTB, and L2 behaves as a crystalline sponge for a variety of guests, showing a higher affinity for aromatic guest molecules. Single-crystal nanoindentation experiments indicate that a high number of specific interactions between the guests and the CP framework result in a high elastic modulus and hardness values. |
Grants: |
European Commission 615954 Ministerio de Economía y Competitividad SEV-2015-0496 Ministerio de Economía y Competitividad SEV-2013-0295 Ministerio de Educación y Ciencia CTQ2013-44670-R Agència de Gestió d'Ajuts Universitaris i de Recerca 2014/SGR/149
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Rights: |
Tots els drets reservats. |
Language: |
Anglès |
Document: |
Article ; recerca ; Versió sotmesa a revisió |
Published in: |
Crystal growth and design, Vol. 17, issue 2 (2017) , p. 846-857, ISSN 1528-7483 |
DOI: 10.1021/acs.cgd.6b01682
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Record created 2018-04-18, last modified 2023-05-30