Metal Acetylacetonates as a Source of Metals for Aqueous Synthesis of Metal-Organic Frameworks
Camur, Ceren (Institut Català de Nanociència i Nanotecnologia)
Pérez-Carvajal, Javier (Institut Català de Nanociència i Nanotecnologia)
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia)
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)

Date:	2018
Abstract:	Demand continues for environmentally sound, high-yielding processes for the large-scale production of metal-organic frameworks (MOFs). Here we describe the use of metal acetylacetonate complexes as an alternative source of metals for the aqueous synthesis of MOFs. We have synthesized several carboxylate-based Zr(IV)-(UiO-66-NH2, Zr-fumarate, UiO-66-(OH)2, UiO-66-COOH and UiO-66-(COOH)2), Fe(III)-(MIL-88A) and Al(III)-(CAU-10) porous MOFs from their corresponding metal acetylacetonates in good yields (typically >85%) and, in some cases, at room temperature.
Grants:	Ministerio de Economía y Competitividad MAT2015-65354-C2-1-R Agència de Gestió d'Ajuts Universitaris i de Recerca 2014/SGR-80 European Commission 615954 European Commission 685727 Ministerio de Economía y Competitividad SEV-2013-0295
Rights:	Tots els drets reservats.
Language:	Anglès
Document:	Article ; recerca ; Versió acceptada per publicar
Subject:	Green synthesis ; Metal-organic frameworks ; Water
Published in:	ACS sustainable chemistry & engineering, Vol. 6, issue 11 (Nov. 2018) , p. 14554-14560, ISSN 2168-0485

DOI: 10.1021/acssuschemeng.8b03180

Post-Print 21 p, 563.4 KB

Supporting Information Post-Print 21 p, 1.9 MB

The record appears in these collections:
Research literature > UAB research groups literature > Research Centres and Groups (research output) > Experimental sciences > Catalan Institute of Nanoscience and Nanotechnology (ICN2)
Articles > Research articles
Articles > Published articles