Web of Science: 1 citations, Scopus: 2 citations, Google Scholar: citations,
Metal Acetylacetonates as a Source of Metals for Aqueous Synthesis of Metal-Organic Frameworks
Avci-Camur, Ceren (Institut Català de Nanociència i Nanotecnologia)
Pérez Carvajal, Javier (Institut Català de Nanociència i Nanotecnologia)
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia)
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)

Date: 2018
Abstract: Demand continues for environmentally sound, high-yielding processes for the large-scale production of metal-organic frameworks (MOFs). Here we describe the use of metal acetylacetonate complexes as an alternative source of metals for the aqueous synthesis of MOFs. We have synthesized several carboxylate-based Zr(IV)-(UiO-66-NH2, Zr-fumarate, UiO-66-(OH)2, UiO-66-COOH and UiO-66-(COOH)2), Fe(III)-(MIL-88A) and Al(III)-(CAU-10) porous MOFs from their corresponding metal acetylacetonates in good yields (typically >85%) and, in some cases, at room temperature.
Note: Número d'acord de subvenció MINECO/MAT2015-65354-C2-1-R
Note: Número d'acord de subvenció AGAUR/2014/SGR-80
Note: Número d'acord de subvenció FP7/615954)
Note: Número d'acord de subvenció H2020/685727
Note: Número d'acord de subvenció MINECO/SEV-2013-0295
Rights: Tots els drets reservats
Language: Anglès.
Document: article ; recerca ; acceptedVersion
Subject: Green synthesis ; Metal-organic frameworks ; Water
Published in: ACS Sustainable Chemistry and Engineering, Vol. 6, issue 11 (Nov. 2018) , p. 14554–14560, ISSN 2168-0485

DOI: 10.1021/acssuschemeng.8b03180


Available from: 2019-11-30
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The record appears in these collections:
Research literature > UAB research groups literature > Research Centres and Groups (scientific output) > Experimental sciences > Catalan Institute of Nanoscience and Nanotechnology (ICN2)
Articles > Research articles
Articles > Published articles

 Record created 2018-10-10, last modified 2019-07-04



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