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Pàgina inicial > Articles > Articles publicats > Introducing asymmetric functionality into MOFs via the generation of metallic Janus MOF particles |
Data: | 2016 |
Resum: | Herein we report a versatile methodology for engineering metallic Janus MOF particles based on desymmetrization at interfaces, whereby each MOF particle is partially coated with a desired metal. We demonstrate that it enables the fabrication of homogeneous Janus MOF particles according to the MOF (ZIF-8, UiO-66 or UiO-66-SH), the metal (Au, Co or Pt), the MOF particle size (from the micrometer to the submicrometer regime) and the metal-film thickness (from 5 nm to 50 nm) employed. We anticipate that our strategy could be applied to impart new functionalities to MOFs, including asymmetric functionalization, magnetic-guidance and motorization. |
Ajuts: | Ministerio de Economía y Competitividad MAT2012-30994 European Commission 615954 Ministerio de Economía y Competitividad RYC-2010-06530 Ministerio de Economía y Competitividad SEV-2013-0295 |
Drets: | Tots els drets reservats. |
Llengua: | Anglès |
Document: | Article ; recerca ; Versió acceptada per publicar |
Publicat a: | Chemical communications, Vol. 52, Issue 29 (April 2016) , p. 5096-5099, ISSN 1364-548X |
Postprint 5 p, 697.8 KB |