Protection strategies for directionally-controlled synthesis of previously inaccessible metal-organic polyhedra (MOPs) : The cases of carboxylate: The amino-functionalised Rh(ii)-MOPs
Albalad, Jorge (Institut Català de Nanociència i Nanotecnologia)
Carné-Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia)
Grancha, Thais (Institut Català de Nanociència i Nanotecnologia)
Hernández López, Laura (Institut Català de Nanociència i Nanotecnologia)
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)

Date:	2019
Abstract:	Herein we report that strategic use of protecting groups in coordination reactions enables directional inhibition that leads to synthesis of highly functionalised metal-organic polyhedra (MOPs), rather than of the extended coordination networks. Using this approach, we functionalised two new porous cuboctahedral Rh(ii)-based MOPs with 24 peripheral carboxylic acid groups or 24 peripheral amino groups.
Grants:	Ministerio de Economía y Competitividad RTI2018-095622-B-I00 Agència de Gestió d'Ajuts Universitaris i de Recerca 2017/SGR-238 European Commission 615954 Ministerio de Economía y Competitividad SEV-2017-0706 Ministerio de Economía y Competitividad IJCI-2016-29802 Ministerio de Economía y Competitividad FJCI2017-31598
Rights:	Tots els drets reservats.
Language:	Anglès
Document:	Article ; recerca ; Versió acceptada per publicar
Published in:	Chemical communications, Vol. 55, Issue 85 (November 2019) , p. 12785-12788, ISSN 1364-548X

DOI: 10.1039/c9cc07083d
PMID: 31591620

Postprint 9 p, 1.3 MB

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Research literature > UAB research groups literature > Research Centres and Groups (research output) > Experimental sciences > Catalan Institute of Nanoscience and Nanotechnology (ICN2)
Articles > Research articles
Articles > Published articles