Hydrothermal synthesis, between 75 and 150°C, of high-charge, ferric nontronites
Decarreau, Alain (Université de Poitiers. UMR 6532 HydrASA. CNRS/INSU)
Petit, Sabine (Université de Poitiers. UMR 6532 HydrASA. CNRS/INSU)
Martin, François (ERT 1074 CNRS Géomatériaux. LMTG-OMP-UPS-IRD. CNRS)
Farges, François (USM 201 - UMR CNRS 7160. Muséum National d'Histoire Naturelle)
Vieillard, Philippe (Université de Poitiers. UMR 6532 HydrASA. CNRS/INSU)
Joussein, Emmanuel (Université de Limoges. UMR 6532 HydrASA. CNRS/INSU)
Data: |
2008 |
Resum: |
High-charge nontronites were synthesized at 75, 90, 100, 110, 125, and 150°C from a silicoferrous starting gel with SiFeNa O. nHO Composition. This gel was oxidized in contact with air and then hydrothermally treated, for a period of 4 weeks, under equilibrium water pressure. The synthesized nontronites were similar to each other, regardless of the synthesis temperature. Their structural formula, obtained from chemical analysis, X-ray diffraction (XRD), and Fourier transform infrared (FTIR), Mössbauer, and X-ray absorption fine structure spectroscopies is: (Si Fe ) Fe O (OH)Na. A strictly ferric end-member of the nontronite series was therefore synthesized for the first time. The uncommon chemistry of the synthesized nontronites, notably the high level of Fe-for-Si substitution, induced particular XRD, FTIR, and differential thermal analysis-thermogravimetric analysis data. The ethylene glycol expandability of the synthetic nontronites was linked to their crystallinity and depended on the nature of the interlayer cation, moving from smectite to vermiculite-like behavior. As the synthesis temperature increased, the crystallinity of the synthesized clays increased. The nontronite obtained at 150°C had the 'best crystallinity', which cannot be improved by increasing synthesis time or temperature. |
Drets: |
Tots els drets reservats. |
Llengua: |
Anglès |
Document: |
Article ; recerca ; Versió publicada |
Matèria: |
FTIR Spectroscopy ;
High-charge Nontronite ;
Mössbauer Spectroscopy ;
XAFS |
Publicat a: |
Clays and Clay Minerals, Vol. 56, Núm. 3 (2008) , p. 322-337, ISSN 1552-8367 |
DOI: 10.1346/CCMN.2008.0560303
16 p, 1.4 MB
Accés restringit a la UAB
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