A self-powered skin-patch electrochromic biosensor
Santiago, Sara ![Identificador ORCID](/img/uab/orcid.ico)
(Universitat Autònoma de Barcelona)
Río-Colín, Diego (Universidad del País Vasco)
Azizkhani, Haniyeh (Universitat Autònoma de Barcelona)
Aller Pellitero, Miguel ![Identificador ORCID](/img/uab/orcid.ico)
(Johns Hopkins University School of Medicine)
Guirado López, Gonzalo ![Identificador ORCID](/img/uab/orcid.ico)
(Universitat Autònoma de Barcelona)
del Campo, F. Javier ![Identificador ORCID](/img/uab/orcid.ico)
(Institut de Microelectrònica de Barcelona)
Fecha: |
2021 |
Resumen: |
One of the limitations of many skin-patch wearable sensors today is their dependence on silicon-based electronics, increasing their complexity and unit cost. Self-powered sensors, in combination with electrochromic materials, allow simplifying the construction of these devices, leading to powerful analytical tools that remove the need for external detection systems. This work describes the construction, by screen-printing, of a self-powered electrochromic device that can be adapted for the determination of metabolites in sweat by the naked eye in the form of a 3 × 15 mm colour bar. The device comprises a lactate oxidase and osmium-polymer -based anode connected to a coplanar 3 × 15 mm Prussian Blue, PB, cathode printed over a transparent poly(3,4-ethylenedioxythiophene) polystyrene sulfonate, PEDOT:PSS electrode. An ion-gel composed of Poly(vinylidene fluoride-co-hexafluoropropylene), PVDF-co-HFP, a gelling agent, and ionic liquid 1-Ethyl-3-methylimidazolium trifluoromethanesulfonate, EMIM-Tf, effectively separates the cathode display from the biosensing anode, protecting it from the sample. Despite its cathodic electrochromism, the PEDOT:PSS has a transmission above 90% and does not mask the Prussian Blue colour change because the cathode does not operate below 0 V vs Ag/AgCl at any time. The sensor displays lactate concentrations in the range of 0-10 mM over the length of the electrochromic display, which has a contrast ratio of 1. 43. Although full response takes up to 24 min, 85% of the colour change is displayed within 10 min. |
Ayudas: |
Agència de Gestió d'Ajuts Universitaris i de Recerca PROD-0000114 Agencia Estatal de Investigación PID2019-106171RB-I00
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Derechos: |
Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, i la comunicació pública de l'obra, sempre que no sigui amb finalitats comercials, i sempre que es reconegui l'autoria de l'obra original. No es permet la creació d'obres derivades. ![Creative Commons](/img/licenses/by-nc-nd.ico) |
Lengua: |
Anglès |
Documento: |
Article ; recerca ; Versió acceptada per publicar |
Materia: |
Electrochromism ;
Biosensors ;
Self-powered devices ;
Wearables ;
Lactate biosensor ;
Sweat sensing |
Publicado en: |
Biosensors & bioelectronics, Vol. 175 (March 2021) , art. 112879, ISSN 1873-4235 |
DOI: 10.1016/j.bios.2020.112879
PMID: 33309218
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Registro creado el 2023-05-09, última modificación el 2024-05-18