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Encapsulation of cationic iridium(iii) tetrazole complexes into a silica matrix : synthesis, characterization and optical properties / Zanoni, Ilaria (National Research Council of Italy. Institute of Science and Technology for Ceramics) ; Fiorini, Valentina (University of Bologna. Department of Industrial Chemistry Toso Montanari) ; Rosado, Marcos (Institut Català de Nanociència i Nanotecnologia) ; Ballesteros, Belén (Institut Català de Nanociència i Nanotecnologia) ; Androulidaki, Maria (IESL-FORTH) ; Blosi, Magda (National Research Council of Italy. Institute of Science and Technology for Ceramics) ; Ortelli, Simona (National Research Council of Italy. Institute of Science and Technology for Ceramics) ; Stagni, Stefano (University of Bologna. Department of Industrial Chemistry Toso Montanari) ; Dondi, Michele (National Research Council of Italy. Institute of Science and Technology for Ceramics) ; Costa, Anna Luisa (National Research Council of Italy. Institute of Science and Technology for Ceramics)
Herein we report the easy incorporation of brightly phosphorescent cationic iridium(iii) tetrazole complexes into a silica based matrix via an easily scalable colloidal process. For this purpose, two cationic Ir(iii) emitters bearing 5-aryl tetrazole ligands (R-CN) were selected: blue [FIrPTZ-Me] (C^N = Fppy; N^N = PTZ-Me-2-(2-methyl-2H-tetrazol-5-yl)pyridine) and red [IrQTZ-Me] (C^N = ppy; N^N = QTZ-Me-2-(2-methyl-2H-tetrazol-5-yl)quinoline). [...]
2018 - DOI (Digital Object Identifier)

10.1039/c8nj01514g
New journal of chemistry, Vol. 42, Issue 12 (June 2018) , p. 9635-9644

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