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34 p, 1.2 MB An optimized glutamate receptor photoswitch with sensitized azobenzene isomerization / Gascón Moya, Marta (Universitat Autònoma de Barcelona. Departament de Química) ; Pejoan, Arnau (Universitat Autònoma de Barcelona. Departament de Química) ; Izquierdo-Serra, Mercè (Institut de Bioenginyeria de Catalunya) ; Pittolo, Silvia (Institut de Bioenginyeria de Catalunya) ; Cabré Segura, Gisela (Universitat Autònoma de Barcelona. Departament de Química) ; Hernando Campos, Jordi (Universitat Autònoma de Barcelona. Departament de Química) ; Alibes, Ramón (Universitat Autònoma de Barcelona. Departament de Química) ; Gorostiza, Pau (Institut de Bioenginyeria de Catalunya) ; Busqué Sánchez, Félix (Universitat Autònoma de Barcelona. Departament de Química)
A new azobenzene-based photoswitch, 2, has been designed to enable optical control of ionotropic glutamate receptors in neurons via sensitized two-photon excitation with NIR light. In order to develop an efficient and versatile synthetic route for this molecule, a modular strategy is described which relies on the use of a new linear fully protected glutamate derivative stable in basic media. [...]
2015 - 10.1021/acs.joc.5b01402
Journal of organic chemistry, Vol. 80, issue 20 (Oct. 2015) , p. 9915-9925  
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