Web of Science: 57 cites, Scopus: 60 cites, Google Scholar: cites,
Performance and stability of mixed FAPbI3(0.85)MAPbBr3(0.15) halide perovskite solar cells under outdoor conditions and the effect of low light irradiation
Reyna, Yegraf (Institut Català de Nanociència i Nanotecnologia)
Salado, Manuel (Abengoa Research)
Kazim, Samrana (Abengoa Research)
Perez-Tomas, Amador (Institut Català de Nanociència i Nanotecnologia)
Ahmad, Shahzada (Abengoa Research)
Lira-Cantu, Monica (Institut Català de Nanociència i Nanotecnologia)

Data: 2016
Resum: We demonstrate for the first time, the real lifetime response of mixed halide perovskite solar cells (PSCs) for >1000 h under outdoor conditions and the exceptional photoresponse observed at low-light intensities attributed to the ionic-electronic nature of the material. The investigated devices were fabricated by utilizing mixed perovskites containing formamidinium (FA) and methylammonium (MA) cations, in a one step solution-process method through a solvent engineering approach. The devices' architecture is FTO/TiO (blocking layer) TiO (mesoporous)/FAPbIMAPbBr/Spiro-OMeTAD/Au. Notably, low short circuit current (J) was observed at low light intensities (<50 W/m) together with high open circuit potential build-up, which resulted in high PCEs. This response is in agreement with a "double electronic-ionic transport" model of the halide perovskite where the ionic component dominates at low light intensities and the electronic component dictates at high light irradiances. Our results highlight the exceptional stability of mixed MA/FA mesoscopic PSCs when operated for >1000 h under real outdoor conditions and the strong ionic component observed at low light irradiation.
Ajuts: MINECO/SEV-2013-0295
MINECO/ENE2013-48816-C5-4-R
MINECO/ENE2016-79282-C5-2-R
MINECO/MAT2015-68994-REDC
AGAUR/2014/SGR-1212
Drets: Tots els drets reservats.
Llengua: Anglès
Document: article ; recerca ; Versió sotmesa a revisió
Matèria: Halide perovskite solar cells ; Hybrid solar cells ; Stability ; ISOS protocols ; Outdoor analyses
Publicat a: Nano Energy, Vol. 30 (December 2016) , p. 570-579, ISSN 2211-2855

DOI: 10.1016/j.nanoen.2016.10.053


Preprint
27 p, 1.3 MB

El registre apareix a les col·leccions:
Documents de recerca > Documents dels grups de recerca de la UAB > Centres i grups de recerca (producció científica) > Ciències > Institut Català de Nanociència i Nanotecnologia (ICN2)
Articles > Articles de recerca
Articles > Articles publicats

 Registre creat el 2019-09-23, darrera modificació el 2021-06-12



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