A copper(II) zig-zag metal-organic coordination polymer : synthesis, crystal structure, topology study, hirshfeld surface analysis and survey different conditions on morphology of a novel nano structure [Cu(L)(SCN)(H2O)2]n.2H2O
Souri, Bagher (University of Sistan and Baluchestan. Department of Chemistry)
Hayati, Payam (Institut Català de Nanociència i Nanotecnologia)
Rezvani, Ali Reza (University of Sistan and Baluchestan. Department of Chemistry)
Mendoza Meroño, Rafael (Universidad de Oviedo. Departamento de Química Física y Analítica)
Janczak, Jan (Institute of Low Temperature and Structure Research)

Data:	2019
Resum:	One copper(II) coordination polymer compound [Cu(L)(SCN)(HO)]. 2HO (1) where L stand for 2-pyridinecarboxylic acid, was synthesized following two different experimental methods, branch tube and sonochemical irradiation nano methods. Independently of the methodology used, the same crystalline phase is obtained for each compound. Single crystal X-ray analyses on compound 1 showed that Cu ions are 6-coordinated. Additionally, H-bonds incorporate the zig-zag chains in 1 into 2D (along (1,1,0) direction) frameworks. Topological analysis shows that the compound 1 is 2C1 net. Hirshfeld surface analysis of compound 1 was studied. Also, theoretical and experimental morphology were studied. The thermal stability of compound 1 was studied by thermal gravimetric. Finally, the role of reaction time and temperature on growth and final morphology of the structures obtained by sonochemical irradiation are investigated. The results indicated that particle size was reduced with increasing sonication power, temperature, sonication time and decreasing concentration of reactant.
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Llengua:	Anglès
Document:	Article ; recerca ; Versió acceptada per publicar
Matèria:	Coordination polymer compound ; Sonochemical process ; Ultrasound irradiation ; Hirshfeld surface analysis ; Morphology
Publicat a:	Inorganic and nano-metal chemistry, Vol. 50, Issue 2 (September 2019) , p. 80-93, ISSN 2470-1564

DOI: 10.1080/24701556.2019.1662040

Postprint 16 p, 2.3 MB

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