Firing tests on clay-rich raw materials from the algarve basin (Southern Portugal) : Study of mineral transformations with temperature
Trindade, Maria José (Universidade de Aveiro. GeoBioTec - GeoBiociências)
Dias, Maria Isabel (Universidade de Aveiro. GeoBioTec - GeoBiociências)
Coroado, Joâo (Universidade de Aveiro. GeoBioTec - GeoBiociências)
Rocha, Fernando (Universidade de Aveiro. GeoBioTec - GeoBiociências)

Data:	2010
Resum:	In cases where the provenance of raw materials used in the manufacture of local archeological ceramics is of interest, a detailed study of thermal transformations of minerals may be useful. The purpose of this study was to measure mineralogical transformations of different types of clays obtained during experimental firing runs, carried out at different temperatures, with the main goal of establishing Algarve reference groups based on the composition of raw material and high-temperature mineralogy, which may be compared with ceramics in studies of provenance. Eleven samples of clay-rich raw materials from the Algarve Basin (southern Portugal) were fired to temperatures ranging from 300 to 1100°C in increments of 100°C under oxidizing conditions. These were chosen to have variable chemical and mineralogical compositions, representing the main compositional range of the clay deposits from the region. Mineralogical and geochemical characterizations of the original clays were carried out by X-ray diffraction (XRD) and X-ray fluorescence (XRF), respectively. Mineral transformations on the fired products were also studied by XRD. Three groups of clays were distinguished according to the type of neoformed high-temperature minerals: (1) non-calcareous clays; (2) clays containing calcite as the only carbonate; and (3) clays with dolomite or dolomite + calcite. Firing of non-calcareous clays produced mullite at 1100-1200°C. Gehlenite and wollastonite formed by firing calcite-rich clays above 900°C, accompanied by anorthite or larnite in samples with small or large calcite contents, respectively. Firing of dolomite-rich clays at temperatures >900°C yielded a member of the gehlenite-åkermanite group and diopside. Anorthite, enstatite, periclase, forsterite, and monticellite may also form in the firing products.
Nota:	Altres ajuts: FCT (SFRH / BD /11020/2002)
Drets:	Aquest material està protegit per drets d'autor i/o drets afins. Podeu utilitzar aquest material en funció del que permet la legislació de drets d'autor i drets afins d'aplicació al vostre cas. Per a d'altres usos heu d'obtenir permís del(s) titular(s) de drets.
Llengua:	Anglès
Document:	Article ; recerca ; Versió publicada
Matèria:	Algarve Basin ; Firing Tests ; High-temperature Minerals ; Mineral Transformations ; X-ray Diffraction
Publicat a:	Clays and Clay Minerals, Vol. 58, Núm. 2 (2010) , p. 188-204, ISSN 1552-8367

DOI: 10.1346/CCMN.2010.0580205

17 p, 2.1 MB  Accés restringit a la UAB

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