Metal-organic framework-derived single atom catalysts for electrocatalytic reduction of carbon dioxide to C1 products
Han, Xu (Institut Català de Nanociència i Nanotecnologia)
Zhang, Ting (Institut Català de Nanociència i Nanotecnologia)
Arbiol i Cobos, Jordi ![Identificador ORCID](/img/uab/orcid.ico)
(Institut Català de Nanociència i Nanotecnologia)
Data: |
2023 |
Resum: |
Electrochemical carbon dioxide reduction reaction (eCO RR) is an efficient strategy to relieve global environmental and energy issues by converting excess CO from the atmosphere to value-added products. Single-atom catalysts (SACs) derived from metal-organic frameworks (MOF), which feature unique active sites and adjustable structures, are emerging as extraordinary materials for eCO RR. By modulating the MOF precursors and their fabrication strategy, MOF-derived SACs with specific-site coordination configuration have been recently designed for the conversion of CO to targeted products. In the first part of this review, MOF synthesis routes to afford well-dispersed SACs along with the respective synthesis strategy have been systematically reviewed, and typical examples for each strategy have been discussed. Compared with traditional M-N active sites, SACs with regulated coordination structures have been rapidly developed for eCO RR. Secondly, the relationship between regulation of the coordination environment of the central metal atoms, including asymmetrical M-N sites, heteroatom doped M-N sites, and dual-metal active sites (M-M sites), and their respective catalytic performance has been systematically discussed. Finally, the challenges and future research directions for the application of SACs derived from MOFs for eCO RR have been proposed. |
Ajuts: |
Agencia Estatal de Investigación PID2020-116093RB-C43 Agència de Gestió d'Ajuts Universitaris i de Recerca 2017/SGR-327 Ministerio de Ciencia e Innovación CEX2021-001214-S
|
Drets: |
Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original. ![Creative Commons](/img/licenses/by.ico) |
Llengua: |
Anglès |
Document: |
Article ; recerca ; Versió publicada |
Publicat a: |
Energy Advances, Vol. 2, Issue 2 (February 2023) , p. 252-267, ISSN 2753-1457 |
DOI: 10.1039/d2ya00284a
El registre apareix a les col·leccions:
Documents de recerca >
Documents dels grups de recerca de la UAB >
Centres i grups de recerca (producció científica) >
Ciències >
Institut Català de Nanociència i Nanotecnologia (ICN2)Articles >
Articles de recercaArticles >
Articles publicats
Registre creat el 2023-10-11, darrera modificació el 2023-11-05