Metal- and covalent-organic framework mixed matrix membranes for CO2 separation : A perspective on stability and scalability
Shan, Meixia (Delft University of Technology. Chemical Engineering Department)
Geng, Xiumei (Zhengzhou University. School of Chemical Engineering)
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia)
Broto-Ribas, Anna (Institut Català de Nanociència i Nanotecnologia)
Ortín-Rubio, Borja (Institut Català de Nanociència i Nanotecnologia)
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Ansaloni, Luca (SINTEF Industry)
Peters, Thijs A. (SINTEF Industry)
Tena, Alberto (University of Valladolid)
Boerrigter, Marcel E. (Leitat Technological Center)
Vermaas, David A. (Delft University of Technology. Chemical Engineering Department)

Data:	2024
Resum:	Membrane technology has attracted great industrial interest in carbon capture and separation owing to the merits of energy-efficiency, environmental friendliness and low capital investment. Conventional polymeric membranes for CO separation suffer from the trade-off between permeability and selectivity. Introducing porous fillers in polymers is one approach to enhance membrane separation performance. Metal-organic frameworks (MOFs), with ordered porous structure and diverse chemical functionalities, are promising fillers to prepare mixed matrix membranes (MMMs) for CO separation. However, the main issue of MOF based MMMs in industry is their stability and processability. This review analyses recent work on stable and scalable MOF based MMMs for CO separation. The typical stable MOFs, MOF-based MMMs and the scalable MOF synthesis are summarized. A large number of MOF-based MMM suffer from instability upon exposure to contaminants. For that reason, we also discuss the use of covalent organic frameworks (COFs) as an alternative to prepare MMMs for CO separation, considering their excellent stability and good compatibility with polymers. Finally, a brief conclusion and current challenges on obtaining scalable and stable MMMs are outlined. This review may provide some guidance for designing high performance MMMs for industrial CO capture and separation to help achieving carbon neutrality.
Ajuts:	Agència de Gestió d'Ajuts Universitaris i de Recerca 2017/SGR-238 Ministerio de Ciencia e Innovación SEV-2017-0706 European Commission 760899
Drets:	Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original.
Llengua:	Anglès
Document:	Article ; recerca ; Versió publicada
Matèria:	Capital investment ; Covalent organic frameworks ; Environmental friendliness ; Membrane separation ; Metalorganic frameworks (MOFs) ; Mixed-matrix membranes ; Ordered porous ; Porous fillers ; Separation performance ; Trade off
Publicat a:	Journal of Membrane Science, Vol. 691 (February 2024) , art. 122258, ISSN 1873-3123

DOI: 10.1016/j.memsci.2023.122258

19 p, 9.2 MB

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