Web of Science: 14 cites, Scopus: 14 cites, Google Scholar: cites,
Continuous one-step synthesis of porous M-XF6-based metal-organic and hydrogen-bonded frameworks
Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia)
Garzon-Tovar, Luis (Institut Català de Nanociència i Nanotecnologia)
Yazdi, Amirali (Institut Català de Nanociència i Nanotecnologia)
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia)
Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró)
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)

Data: 2017
Resum: Metal-organic frameworks (MOFs) built up from connecting M-XF₆ pillars through N-donor ligands are among the most attractive adsorbents and separating agents for CO₂ and hydrocarbons today. The continuous, one-step spray-drying synthesis of several members of this isoreticular MOF family varying the anionic pillar (XF₆=[SiF₆]²⁻ and [TiF₆]²⁻), the N-donor organic ligand (pyrazine and 4,4'-bipyridine) and the metal ion (M=Co, Cu and Zn) is demonstrated here. This synthetic method allows them to be obtained in the form of spherical superstructures assembled from nanosized crystals. As confirmed by CO₂ and N₂ sorption studies, most of the M-XF₆-based MOFs synthesised through spray-drying can be considered "ready-to-use" sorbents as they do not need additional purification and time consuming solvent exchange steps to show comparable porosity and sorption properties with the bulk/single-crystal analogues. Stability tests of nanosized M-SiF₆-based MOFs confirm their low stability in most solvents, including water and DMF, highlighting the importance of protecting them once synthesised. Finally, for the first time it was shown that the spray-drying method can also be used to assemble hydrogen-bonded open networks, as evidenced by the synthesis of MPM-1-TIFSIX.
Ajuts: MINECO/MAT2012-30994
AGAUR/2014/SGR-80
European Commission 615954
European Commission 685727
AGAUR/2014/BP-B-00155
MINECO/RYC-2010-06530
MINECO/SEV-2013-0295
Drets: Tots els drets reservats.
Llengua: Anglès
Document: article ; recerca ; Versió acceptada per publicar
Matèria: Fluorinated materials ; Metal-organic frameworks ; Spray-drying ; Stability
Publicat a: Chemistry, Vol. 23, Issue 28 (May 2017) , p. 6829-6835, ISSN 1521-3765

DOI: 10.1002/chem.201605507


Post-print
22 p, 989.8 KB

Supporting Information
23 p, 2.2 MB

El registre apareix a les col·leccions:
Documents de recerca > Documents dels grups de recerca de la UAB > Centres i grups de recerca (producció científica) > Ciències > Institut Català de Nanociència i Nanotecnologia (ICN2)
Articles > Articles de recerca
Articles > Articles publicats

 Registre creat el 2018-07-25, darrera modificació el 2021-07-19



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