Web of Science: 13 cites, Scopus: 10 cites, Google Scholar: cites
Large edge magnetism in oxidized few-layer black phosphorus nanomeshes
Nakanishi, Yudai (Aoyama Gakuin Daigaku)
Ishi, Ayumi (Aoyama Gakuin Daigaku)
Ohata, Chika (Aoyama Gakuin Daigaku)
Soriano, David (Institut Català de Nanociència i Nanotecnologia)
Iwaki, Ryo (Aoyama Gakuin Daigaku.)
Nomura, Kyoto (Aoyama Gakuin Daigaku)
Hasegawa, Miki (Aoyama Gakuin Daigaku.)
Nakamura, Taketomo (Tōkyō Daigaku)
Katsumoto, Shingo (Tōkyō Daigaku)
Roche, Stephan (Institut Català de Nanociència i Nanotecnologia)
Haruyama Junji (Aoyama Gakuin Daigaku.)

Data: 2017
Resum: The formation and control of a room-temperature magnetic order in two-dimensional (2D) materials is a challenging quest for the advent of innovative magnetic- and spintronic-based technologies. To date, edge magnetism in 2D materials has been experimentally observed in hydrogen (H)-terminated graphene nanoribbons (GNRs) and graphene nanomeshes (GNMs), but the measured magnetization remains far too small to allow envisioning practical applications. Herein, we report experimental evidences of large room-temperature edge ferromagnetism (FM) obtained from oxygen (O)-terminated zigzag pore edges of few-layer black phosphorus (P) nanomeshes (BPNMs). The magnetization values per unit area are ~100 times larger than those reported for H-terminated GNMs, while the magnetism is absent for H-terminated BPNMs. The magnetization measurements and the first-principles simulations suggest that the origin of such a magnetic order could stem from ferromagnetic spin coupling between edge P with O atoms, resulting in a strong spin localization at the edge valence band, and from uniform oxidation of full pore edges over a large area and interlayer spin interaction. Our findings pave the way for realizing high-efficiency 2D flexible magnetic and spintronic devices without the use of rare magnetic elements.
Nota: Número d'acord de subvenció EC/FP7/604391
Nota: Número d'acord de subvenció MINECO/FIS2015-67767-P
Nota: Número d'acord de subvenció MINECO/SEV-2013-0295
Drets: Tots els drets reservats
Llengua: Anglès.
Document: article ; recerca ; acceptedVersion
Matèria: Black phosphorus nanomesh ; Edge magnetism ; Oxygen termination ; Rare-metal free ; Spintronics ; Zigzag edge
Publicat a: Nano research, Vol. 10, no. 2 (Feb. 2017) , p. 718-728, ISSN 19980124

DOI: 10.1007/s12274-016-1355-8


Post-print
10 p, 1.5 MB

El registre apareix a les col·leccions:
Documents de recerca > Documents dels grups de recerca de la UAB > Centres i grups de recerca (producció científica) > Ciències > Institut Català de Nanociència i Nanotecnologia (ICN2)
Articles > Articles de recerca
Articles > Articles publicats

 Registre creat el 2018-04-30, darrera modificació el 2019-02-02



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