On the Computational Design of Azobenzene-Based Multi-State Photoswitches
Moreno Ferrer, Miquel (Universitat Autònoma de Barcelona. Departament de Química)
Lluch López, Josep Maria (Universitat Autònoma de Barcelona. Institut de Biotecnologia i de Biomedicina "Vicent Villar Palasí")
Gelabert Peiri, Ricard (Universitat Autònoma de Barcelona. Departament de Química)
Date: |
2022 |
Abstract: |
In order to theoretically design multi-state photoswitches with specific properties, an exhaustive computational study is first carried out for an azobenzene dimer that has been recently synthesized and experimentally studied. This study allows for a full comprehension of the factors that govern the photoactivated isomerization processes of these molecules so to provide a conceptual/computational protocol that can be applied to generic multi-state photoswitches. From this knowledge a new dimer with a similar chemical design is designed and also fully characterized. Our theoretical calculations predict that the new dimer proposed is one step further in the quest for a double photoswitch, where the four metastable isomers could be selectively interconverted through the use of different irradiation sequences. |
Grants: |
Ministerio de Ciencia e Innovación PID2020-113764GB-I00
|
Rights: |
Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original. |
Language: |
Anglès |
Document: |
Article ; recerca ; Versió publicada |
Published in: |
International journal of molecular sciences, Vol. 23, Núm. 15 (August 2022) , art. 8690, ISSN 1422-0067 |
DOI: 10.3390/ijms23158690
PMID: 35955820
The record appears in these collections:
Research literature >
UAB research groups literature >
Research Centres and Groups (research output) >
Health sciences and biosciences >
Institut de Biotecnologia i de Biomedicina (IBB)Articles >
Research articlesArticles >
Published articles
Record created 2022-09-09, last modified 2023-10-01